Journal of Organic Chemistry p. 951 - 954 (1982)
Update date:2022-08-04
Topics:
Gassman, Paul G.
Miura, Asako
Miura, Takashi
(Phenylseleno)dimethylsulfonium tetrafluoroborate was found to be a highly reactive selenating agent for electron-rich aromatic compounds such as aromatic amines, phenols, and aromatic ethers.Reaction took place readily at 0-25 deg C to give ca. 50percent yields of substitution para to the activating substituent.In general, anilines gave better yields then anisoles or phenols.
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Doi:10.1016/S0040-4039(01)81909-2
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(1982)Doi:10.1021/ja00371a022
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(1981)