Journal of the Chemical Society, Dalton Transactions p. 2429 - 2433 (1981)
Update date:2022-09-26
Topics:
Peloso, Arnaldo
The kinetics and equilibria of the reversible reactions trans-A linear free-energy relationship of the type a value of α of 0.75 exists for the activation and standard free energies of mer -->trans reactions where a dissociative mechanism is considered to be operative.When X(n-) is SCN(-), N3(-), or NO2(-), the mer -->trans reactions are acid-catalyzed, through protonation of the leaving group.
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