Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex

DOI: 10.1021/jo00053a007

Source and publish data:

Journal of Organic Chemistry p. 16 - 17 (1993)

Update date:2022-08-04

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Authors:

Tsuji, Yasushi

Yamada, Naoaki

Tanaka, Shinsuke

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Article abstract of DOI:10.1021/jo00053a007

Allylic carbonates and acetates are cyanated with trimethylsilyl cyanide in the presence of a catalytic amount (5 mol percent based on the allylic substrates) od Pd(PPh3)4 or Pd(CO)(PPh3)3 in THF under reflux to afford β,γ-unsaturated nitriles in high yields.

Full text of DOI:10.1021/jo00053a007

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