Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex

DOI: 10.1021/jo00053a007

Source and publish data:

Journal of Organic Chemistry p. 16 - 17 (1993)

Update date:2022-08-04

Topics:

Authors:

Tsuji, Yasushi

Yamada, Naoaki

Tanaka, Shinsuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00053a007

Allylic carbonates and acetates are cyanated with trimethylsilyl cyanide in the presence of a catalytic amount (5 mol percent based on the allylic substrates) od Pd(PPh3)4 or Pd(CO)(PPh3)3 in THF under reflux to afford β,γ-unsaturated nitriles in high yields.

Full text of DOI:10.1021/jo00053a007

Products guided by the article

Product name:(Z)-1-cyano-2-hexene

Cas No:80639-55-0

R&D Labs maybe for 80639-55-0

Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Jiangsu Fengming Chemical Technology Co., Ltd

Contact:+86-512-68026040

Address:1-6F 606, No.9 Dengwei Road, New & Hi-Tech Industrial Development Zone
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China

Relevant to this article

A convenient chemoenzymatic synthesis of (R)-(-) and (S)-(+)-homo-β- proline

Doi:10.1016/j.tetasy.2004.08.036
(2004)
Synthesis of some new formazans as potential antiviral agents

Doi:10.1002/ardp.19813141204
(1981)
Sustainable catalytic protocols for the solvent free epoxidation and: Anti -dihydroxylation of the alkene bonds of biorenewable terpene feedstocks using H₂O₂ as oxidant

Doi:10.1039/c9gc03208h
(2020)
Synthesis of some new derivatives of 4-hydrazino-5H-pyridazino[4,5-b]indole

Doi:10.1002/jhet.5570180808
(1981)
The nephritogenic glycopeptide from rat glomerular basement membrane. Synthesis of O-(α-D-glucopyranosyl)-1→6)-O-β-D-glucopyranosyl-(1→6)-N-(L-β-aspartyl)-α-D-glucopyranosylamine (α-D-Glc-(1→6)-α-D-Glc-(1→Asn))

Doi:10.1248/cpb.29.3196
(1981)
Synthesis and reactions of α-fluoro-α-amino amides

Doi:10.1016/j.tet.2008.11.061
(2009)

Article Doi