Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex

DOI: 10.1021/jo00053a007

Source and publish data:

Journal of Organic Chemistry p. 16 - 17 (1993)

Update date:2022-08-04

Topics:

Authors:

Tsuji, Yasushi

Yamada, Naoaki

Tanaka, Shinsuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00053a007

Allylic carbonates and acetates are cyanated with trimethylsilyl cyanide in the presence of a catalytic amount (5 mol percent based on the allylic substrates) od Pd(PPh3)4 or Pd(CO)(PPh3)3 in THF under reflux to afford β,γ-unsaturated nitriles in high yields.

Full text of DOI:10.1021/jo00053a007

Products guided by the article

Product name:(Z)-1-cyano-2-hexene

Cas No:80639-55-0

R&D Labs maybe for 80639-55-0

Hangzhou Taiyan Trading Co., Ltd(expird)

Contact:+86-13777583958

Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
NanJing Rate Biochemicals CO., LTD

Contact:+86-25-84931986

Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Jitat Company Ltd

Contact:852-27701081

Address:Room 2509, New Tech Plaza, 34 Tai Yau St., San Po Kong, HK

Relevant to this article

A convenient chemoenzymatic synthesis of (R)-(-) and (S)-(+)-homo-β- proline

Doi:10.1016/j.tetasy.2004.08.036
(2004)
Synthesis of some new formazans as potential antiviral agents

Doi:10.1002/ardp.19813141204
(1981)
Sustainable catalytic protocols for the solvent free epoxidation and: Anti -dihydroxylation of the alkene bonds of biorenewable terpene feedstocks using H₂O₂ as oxidant

Doi:10.1039/c9gc03208h
(2020)
Synthesis of some new derivatives of 4-hydrazino-5H-pyridazino[4,5-b]indole

Doi:10.1002/jhet.5570180808
(1981)
The nephritogenic glycopeptide from rat glomerular basement membrane. Synthesis of O-(α-D-glucopyranosyl)-1→6)-O-β-D-glucopyranosyl-(1→6)-N-(L-β-aspartyl)-α-D-glucopyranosylamine (α-D-Glc-(1→6)-α-D-Glc-(1→Asn))

Doi:10.1248/cpb.29.3196
(1981)
Synthesis and reactions of α-fluoro-α-amino amides

Doi:10.1016/j.tet.2008.11.061
(2009)

Article Doi