Biogenesis of Epidithiadioxopiperazines. Nucleophilic Additions to Benzene Oxide and sym-Oxepin Oxide

DOI: 10.1021/jo00347a028

Source and publish data:

Journal of Organic Chemistry p. 1509 - 1512 (1982)

Update date:2022-08-04

Topics:

Authors:

Rastetter, William H.

Chancellor, Toni

Richard, Thomas J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00347a028

The additions of amine nucleophiles to benzene oxide (10) and to sym-oxepin oxide (14) serve as models for the biogenesis of the epidithiadioxopiperazines of the gliotoxin and aranotin family.Also reported are the additions of a thiolate and an amide anio

Full text of DOI:10.1021/jo00347a028

Products guided by the article

Product name:(1R,6R)-6-Butylamino-cyclohexa-2,4-dienol

Cas No:80764-83-6

R&D Labs maybe for 80764-83-6

Acorn PharmaTech Co., Ltd

Contact:86-25-58619180

Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district

Relevant to this article

Kinetics of Monomerization or Polymerization Reaction for Bis(N-phenyl-salicylideneaminato)nickel(II) and Bis(N-methylsalicylideneaminato)nickel(II) in Solid Phase

Doi:10.1246/bcsj.54.3361
(1981)
Synthesis of phenyl α- and β-L-arabinofuranoside

Doi:10.1016/S0008-6215(00)80806-X
(1982)
The chemistry of indoles. XVI. A convenient synthesis of substituted indoles carrying a hydroxy group, a halogeno group, or a carbon side chain at the 4-position via 4-indolediazonium salts and a total synthesis of (±)-6,7-secoagroclavine

Doi:10.1248/cpb.29.3145
(1981)
Investigations of β-sultones, V: On the reaction of vicinal polycarbonyl compounds with alkanesulfonyl halides and triethylamine, Part 2.

Doi:10.1002/ardp.19823150114
(1982)
Synthesis of highly selective lysosomal markers by coupling 2-(2′-hydroxyphenyl)benzothiazole (HBT) with benzothiazolium cyanine (Cy): the impact of substituents on selectivity and optical properties

Doi:10.1039/c9tb01672d
(2019)
A Stereospecific Total Synthesis of (3R^*,5S^*,9S^*)-Gephyrotoxin 223AB

Doi:10.1021/jo00244a006
(1988)

Article Doi