Biogenesis of Epidithiadioxopiperazines. Nucleophilic Additions to Benzene Oxide and sym-Oxepin Oxide

DOI: 10.1021/jo00347a028

Source and publish data:

Journal of Organic Chemistry p. 1509 - 1512 (1982)

Update date:2022-08-04

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Authors:

Rastetter, William H.

Chancellor, Toni

Richard, Thomas J.

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Article abstract of DOI:10.1021/jo00347a028

The additions of amine nucleophiles to benzene oxide (10) and to sym-oxepin oxide (14) serve as models for the biogenesis of the epidithiadioxopiperazines of the gliotoxin and aranotin family.Also reported are the additions of a thiolate and an amide anio

Full text of DOI:10.1021/jo00347a028

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