
Tetrahedron Letters p. 2001 - 2004 (1980)
Update date:2022-08-02
Topics:
Bloodworth, A. J.
Eggelte, H. J.
3-Cyclopentenyl hydroperoxide 8 has been prepared from cyclopentadiene via hydroboration and autoxidation.Bromination of 8 followed by treatment with an appropriate silver salt has afforded the 5-substituted-2,3-dioxabicyclo<2.2.1>heptanes 11 (endo-bromo), 13 (exo-bromo), and 12 (exo-trifluoroacetoxy).
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Doi:10.1248/cpb.29.3118
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(2017)