Regioselective ring opening of epoxides with lithium azide

DOI: 10.1055/s-1992-26233

Source and publish data:

Synthesis p. 821 - 822 (1992)

Update date:2022-08-03

Topics:

Authors:

Guy Guy

Doussot Doussot

Ferroud Ferroud

Garreau Garreau

Godefroy-Falguieres

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1992-26233

Regioselective ring opening of substituted phenyloxirane was achieved with lithium azide/hexamethylphosphoramide by attack of azide at the non-benzylic position of the epoxide, leading to 1-aryl-2-azidoethanol.

Full text of DOI:10.1055/s-1992-26233

Products guided by the article

Product name:2-(2,4-Dimethoxy-phenyl)-oxirane

Cas No:80860-19-1

R&D Labs maybe for 80860-19-1

Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China

Relevant to this article

Doi:10.1021/ja01262a060
(1942)
Thermal Rearrangements of 2-Cyclopropylcycloalk-2-enones

Doi:10.1039/P19810003147
(1981)
Chemistry of Higher Order Mixed Organocuprates. 2. Reactions of Epoxides

Doi:10.1021/ja00372a032
(1982)
Structure-Activity Relationships of Nogalamycin Analogues

Doi:10.1021/jm00347a016
(1982)
1,2,3,4-Tetrahydrophthalazines, II: Derivatives r375w1 =2,3,4,5,7,12-hexahydro-1H-[1,2,5]triazepino[1,2-b]phthalaz ine-1,5-dione r377w1.r378w2 =2,3,4,5,7,12-HEXAHYDRO-1H-(1,2,5)TRIAZEPIN[1,2-b]PHTHALAZI N-1,5-DION-DERIVATE of 2,3,4,5,7,12-hexahydro-1H-AD1

Doi:10.1002/ardp.19823150206
(1982)
Reactions at High Pressures. <3 + 2> Dipolar Cycloaddition of Nitrones with Vinyl Ethers

Doi:10.1021/jo00132a014
(1982)

Article Doi