Journal of the Chemical Society. Perkin transactions I p. 3083 - 3086 (1981)
Update date:2022-08-02
Topics:
Robins, David J.
Sweeney, John R.
The biosynthesis of the retronecine (3) portion of the pyrrolizidine alkaloid retrorsine (1) present in Senecio isatideus plants has been studied with the aid of 14C-labelled precursors.Putrescine (5), spermidine (6), and spermine (7), are the most efficient precursors of the pyrrolizidine ring.Degradations of labelled retronecine samples indicated that two molecules of each precursor are utilised, and that from these two molecules, a symmetrical intermediate of the type C4-N-C4 is formed and converted into retronecine.
View MoreContact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Hangzhou innopharma technology Co,.Ltd.(expird)
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
Contact:+86-571-86491666
Address:SHI XIANG ROAD
Shanghai Bojing Chemical Co., Ltd.
Contact:021-37122233
Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
Doi:10.1016/S0040-4039(01)92353-6
(1981)Doi:10.1055/s-2006-947349
(2006)Doi:10.1248/cpb.30.158
(1982)Doi:10.1016/j.bmc.2021.116222
(2021)Doi:10.1139/v86-172
(1986)Doi:10.1016/S0040-4039(00)93663-3
(1980)
