Journal of the Chemical Society. Chemical communications p. 1094 - 1095 (1981)
Update date:2022-08-02
Topics:
Bennetau, Bernard
Pillot, Jean-Paul
Dunogues, Jacques
Calas, Raymond
Starting from 3-methylbut-1-yn-3-ol, a short synthesis of α,α-dimethylallyltrimethylsilane (a selective prenylation reagent) has been achieved in 47percent overall yield; several other unsaturated organosilicon intermediates of wide potential utility in organic synthesis are also prepared.
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