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Attempted Amplification of Optical Activity by Crystallization of Chiral Crystals of Photopolymerizing Dienes in the Presence of Their Topochemical Products

DOI: 10.1021/ja00376a030

Source and publish data:

Journal of the American Chemical Society p. 3429 - 3434 (1982)

Update date:2022-08-04

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Authors:

Mil, Jan vanMil, Jan van

Addadi, LiaAddadi, Lia

Gati, EdnaGati, Edna

Lahav, MeirLahav, Meir

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Article abstract of DOI:10.1021/ja00376a030

Monomeric dienes 1-7, which pack in chiral crystal structures and yield upon irradiation chiral dimers, trimers, and oligomers, have beeen crystallized in the presence of small amounts of their photoproducts ("impurities").An efficient asymmetric inductio

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Full text of DOI:10.1021/ja00376a030

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Product name:(1R,2R,3R,4R)-2-{4-[(E)-2-((R)-sec-Butoxycarbonyl)-vinyl]-phenyl}-1-cyano-4-[4-((E)-2-cyano-2-ethoxycarbonyl-vinyl)-phenyl]-cyclobutane-1,3-dicarboxylic acid 3-((R)-sec-butyl) ester 1-ethyl ester

Cas No:81445-52-5

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