Superoxide-, tert-Butoxide-, and Hydroxide-Mediated Autoxidation of 3-Oxo-Δ4 Steroids in Aprotic Media

DOI: 10.1021/jo00135a038

Source and publish data:

Journal of Organic Chemistry p. 2818 - 2819 (1982)

Update date:2022-09-26

Topics:

Authors:

Frimer, Aryeh A.

Gilinsky-Sharon, Pessia

Hameiri, Judith

Aljadeff, Gladis

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Article abstract of DOI:10.1021/jo00135a038

The course of the base-catalyzed autoxidation of 3-oxo-Δ⁴ steroids in aprotic media differs sharply both in yield and product distribution from that reported for protic solvents and involves the oxygenation of the kinetic dienolate.

Full text of DOI:10.1021/jo00135a038

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