A CONVENIENT SYNTHESIS OF BENZYLMETHYLCHLOROSILANES BY THE PALLADIUM-CATALYZED DECHLORINATIVE SILYLATION OF BENZYLIC CHLORIDES WITH METHYLCHLORODISILANES

DOI: 10.1246/cl.1982.399

Source and publish data:

Chemistry Letters p. 399 - 400 (1982)

Update date:2022-07-29

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Authors:

Matsumoto, Hideyuki

Kasahara, Miyuki

Matsubara, Ikuya

Takahashi, Masatoshi

Nakano, Taichi

Nagai, Yoichiro

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Article abstract of DOI:10.1246/cl.1982.399

Benzylmethylchlorosilanes were prepared in high yields by the dechlorinative silylation of benzylic chlorides with methylchlorodisilanes MenSi2CI6-n (n = 2, 3, and 4) in the presence of a catalytic amount of Pd(PPh3)4.

Full text of DOI:10.1246/cl.1982.399

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