Journal of the Chemical Society. Perkin transactions II p. 205 - 210 (1982)
Update date:2022-08-05
Topics:
Hammond, Philip J.
Scott, Graham
Hall, C. Dennis
The reactions of a variety of 1-X-3,4-dimethyl-Δ3-phospholens (where X=Br, Me, Ph, NMe2, SEt, H, and OR) with diethyl peroxide are described.The rates of reaction show a broad correlation with the 31P n.m.r. chemical shifts of the starting phospholens, with low field shifts corresponding to the highest reactivity.The results are discussed in terms of the biphilic mechanism for the reaction of trico-ordinate phosphorus compounds with weak ?-bonds.
View MoreChengdu NoVi Biotechnology Co., Ltd.(expird)
Contact:13551243286/028-81458053
Address:NO.168-1-224 JULONG ROAD WUHOU DISTRICT, CHENGDU CITY,SICHUAN PROVINCE
Contact:+86-571-87859231, 87859237, 87859239
Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053
Shanghai Sungo Technology Chemical Co., Ltd
Contact:0086-21-51385579
Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Contact:86-898-65311214
Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Engineering Research Center of Pesticide, Heilongjiang Province
Contact:+86-451-86609001
Address:No.74 of Xuefu Road, Nangang District,
Doi:10.1080/10286020.2015.1030400
(2015)Doi:10.1021/jf020660i
(2003)Doi:10.1007/BF00506437
(1983)Doi:10.1246/bcsj.56.2527
(1983)Doi:10.1021/ja0470158
(2004)Doi:10.1016/j.tetasy.2004.11.023
(2004)
