Bulletin of the Chemical Society of Japan p. 1092 - 1096 (1982)
Update date:2022-08-03
Topics:
Koto, Shinkiti
Morishima, Naohiko
Kawahara, Reiko
Ishikawa, Katsuhiko
Zen, Shonosuke
Titanium tetrachloride rapidly anomerizes methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside in dichloromethane at 25 deg C.Evidence for the proposal that the benzyloxymethyl group on C-5 and the ring oxygen of the glucoside cooperate to prompt the reaction is described.The reagent anomerizes the interglycosidic linkage of several disaccharide derivatives.
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