Electrochemical Reduction of 2-Iodooctane and 2-Bromooctane at Mercury Cathodes in Dimethylformamide

DOI: 10.1021/jo00139a003

Source and publish data:

Journal of Organic Chemistry p. 3397 - 3403 (1982)

Update date:2022-08-02

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Authors:

Mbarak, Mohammad S.

Peters, Dennis G.

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Article abstract of DOI:10.1021/jo00139a003

In dimethylformamide containing tetraalkylammonium perchlorates, a pulse polarogram for 2-iodooctane exhibits a pair of waves of identical height, attributed to stepwise reduction to the sec-octyl radical and carbanion, respectively.In contrast, 2-bromooc

Full text of DOI:10.1021/jo00139a003

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