SOLVOLYSIS OF 2-m-CHOLOROBENZOYLOXY-4-ISOPROPYL-2H-1,4-THIAZIN-3-ONE GENERATION OF A STABLE CARBOCATION

DOI: 10.1016/S0040-4039(00)85760-3

Source and publish data:

Tetrahedron Letters p. 4963 - 4964 (1982)

Update date:2022-08-05

Topics:

Authors:

Hojo, M.

Masuda, R.

Ichi, T.

Yoshinaga, K.

Yamada, M.

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Article abstract of DOI:10.1016/S0040-4039(00)85760-3

The title compound 2b undergoes nucleophilic substitution reactions with exclusive alkyl-oxygen bond fission and its rate of solvolysis is highly sensitive toward change in polarity of solvents, as is shown by its highest m-value of all reported so far in logk - logk₀ = mY.

Full text of DOI:10.1016/S0040-4039(00)85760-3

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