Insertion of Carbon Dioxide and of Unsaturated Carbon Compounds into the Platinum-Nitrogen Bond: the X-Ray Crystal Structure of cyclo>(PPh3)2

Article abstract of DOI:10.1039/c39820000265

Pt(PhNO)(PPh3)2 reacts with unsaturated carbon compounds such as carbon dioxide, carbon disulphide, alkenes, and dimethyl acetylenedicarboxylate to give 1:1 adducts; X-ray studies on the adduct formed with carbon dioxide, cyclo>(PPh3)2, show that the entering molecule is inserted into the platinum-nitrogen bond of the η²-bonded nitroso ligand.

Full text of DOI:10.1039/c39820000265

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