Crystalline Alkyl-lithiums from α-Trimethylsilyl-substituted o-Xylenes; X-Ray Crystal Structure of 2> (tmeda = Me2NCH2CH2NMe2)

DOI: 10.1039/c39820000014

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 14 - 15 (1982)

Update date:2022-08-03

Topics:

Authors:

Lappert, Michael F.

Raston, Colin L.

Skelton, Brian W.

White, Allan H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000014

Reaction of (R, R', R'', R''' = H or SiMe3) with LiBuⁿ in n-hexane in the presence of Me2NCH2CH2NMe2 (tmeda) or MeN(CH2CH2NMe2)2 (pmdeta) results in selective lithiation of the α-carbon in a manner dependent on the na

Full text of DOI:10.1039/c39820000014

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-(Bis-trimethylsilanyl-methyl)-2-trimethylsilanylmethyl-benzene

Cas No:82452-62-8

R&D Labs maybe for 82452-62-8

Leshan Kai Yada Photoelectric Technology Co., Ltd.,

website:http://www.kydmaterials.com

Contact:0833-5603116

Address:Airport road Jiajiang county, Sichuan province,China
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Hebei Tete Trade Co., Ltd.

Contact:86-311-83160559

Address:shijiazhuang
Win-Win chemical Co.Ltd

website:http://www.win-winchemical.com

Contact:0086-577-64498589

Address:6F, No. 396 Xingping Road, Longwan Industrial Zone, Wenzhou City, Zhejiang, 325000 P.R.China
Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China

Relevant to this article

Doi:10.1021/ja01552a069
(1958)
Synthesis and Some Reactions of Diethyl 1-Methylthio-1(Z),3-butadienephosphonate

Doi:10.1055/s-1982-29810
(1982)
Alkylation of potassium 1-(N-benzyloxycarbonyl-amino)alkylphosphonates and phosphinates in the presence of 18-crown-6

Doi:10.1080/00397919508015491
(1995)
Efficient synthesis of enantiomerically pure α-alkyl cyclopropanecarbonitrile derivatives from pyrazolines

Doi:10.1021/ol047937f
(2004)
α-Methyl Functionalization of Electron-Poor Heterocycles: Chloromethyl Derivatives of 2,2'-Bipyridines

Doi:10.1021/jo00142a022
(1982)
Enzymatic resolution of racemic glycals: An application of the wong acylation method

Doi:10.1016/0040-4039(91)80067-G
(1991)

Article Doi