Crystalline Alkyl-lithiums from α-Trimethylsilyl-substituted o-Xylenes; X-Ray Crystal Structure of 2> (tmeda = Me2NCH2CH2NMe2)

DOI: 10.1039/c39820000014

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 14 - 15 (1982)

Update date:2022-08-03

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Authors:

Lappert, Michael F.

Raston, Colin L.

Skelton, Brian W.

White, Allan H.

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Article abstract of DOI:10.1039/c39820000014

Reaction of (R, R', R'', R''' = H or SiMe3) with LiBuⁿ in n-hexane in the presence of Me2NCH2CH2NMe2 (tmeda) or MeN(CH2CH2NMe2)2 (pmdeta) results in selective lithiation of the α-carbon in a manner dependent on the na

Full text of DOI:10.1039/c39820000014

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