Effect of Remote Substituents upon the Long-Range Aryl Migration and Electrocyclic Ring Opening of exo-3,3-Diaryltricyclo2,4>octan-anti-8-yl Tosylates in Solvolysis

DOI: 10.1021/jo00140a026

Source and publish data:

Journal of Organic Chemistry p. 3721 - 3730 (1982)

Update date:2022-08-02

Topics:

Authors:

Wilt, James W.

Curtis, Veronica A.

O-Yang, Counde

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Article abstract of DOI:10.1021/jo00140a026

The processes of long-range aryl migration (LRAM) and electrocyclic ring opening (ERO) that occur in the solvolysis of the title substrates have been investigated with respect to their relative timing.By substituting an electron-withdrawing group (CN) or

Full text of DOI:10.1021/jo00140a026

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