Reaction of Nickel(I) Complexes conntining Arsine Ligands with Electron-deficient Olefins. Dianionic and Neutral Olefin Ligands in Nickel(II) and Nickel(III) Complexes

DOI: 10.1039/DT9820000535

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 535 - 540 (1982)

Update date:2022-09-26

Topics:

Authors:

Booth, Brian L.

McAuliffe, Charles A.

Stanley, Grahame L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9820000535

The reaction of 4 2 complex, from which can be obtained the BPh4(1-) and PF6(1-)derivatives.Infrared spetra and other measurements allow the assignment of a cis-bridging dianionic tcne(2-) ligand.Reaction of 4 with 7,7,8,8-tetracyanoquinodimethane (tcnq) in a 1:3 ratio gives the planar ClO4; this, and the BPh4(1-) derivative, are diamagnetic and contain the cis-bridging tcnq(2-) dianion.Emoloying greater amounts of tcnq in the d⁷ nickel(III) five-co-ordinate species 2, which exhibits an isotropic e.s.r. signal, g = 2.5, and μ_eff = 1.88 μβ.Reaction of the five-co-ordinate ClO4 with tcne yields either ClO4 (X = Cl or NCS) or X (X = Cl, Br, or I).Both of these types of of complexes are six-co-ordinate and contain N-bonded unidentate neutral tcne ligands.We have obtained no evidence for olefinic bonding in any of these complexes.

Full text of DOI:10.1039/DT9820000535

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Ni((CH₃)(C₆H₅)As(CH₂)2As(C₆H₅)(CH₃))2((NC)2CC(CN)2)2}⁽²⁺⁾*ClO₄^(1-)*Cl^(1-)

Cas No:82569-37-7

R&D Labs maybe for 82569-37-7

Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Nanjing Yuance Industry&Trade Co., Ltd.

website:http://www.njyuance.cn/

Contact:+86-25-85439097

Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Chemtrade International ( China )

Contact:+86-532-86893005

Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
Heliosense Biotechnologies, Inc.

website:https://www.heliosense.com/

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506

Relevant to this article

Hydroxy- and amino-substituted piperidinecarboxylic acids as γ-aminobutyric acid agonists and uptake inhibitors

Doi:10.1021/jm00352a012
(1982)
Pyrimidine N-oxides. IV. The N,N'-dihydroxy derivatives of phenobarbital and veronal

Doi:10.1071/CH9820795
(1982)
THE ACID INDUCED DECOMPOSITION OF 7-SUBSTITUTED 3-DIAZO-2-NORBORNANONES.THE STRUCTURES OF THE PRODUCTS AND THEIR DISTRIBUTION

Doi:10.1016/S0040-4039(00)81942-5
(1983)
The Baylis-Hillman acetates in organic synthesis: Unprecedented sodium nitrite induced intramolecular Friedel-Crafts cyclization of secondary nitro compounds

Doi:10.1039/c4ra03573a
(2014)
Imide-catalyzed oxidation system: Sulfides to sulfoxides and sulfones

Doi:10.1021/jo100719w
(2010)
Benzyne 1,2,4-Trisubstitution and Dearomative 1,2,4-Trifunctionalization

Doi:10.1021/jacs.1c04389
(2021)

Article Doi