CYCLOPALLADATED IMINES IN SYNTHESIS: THE PREPARATION OF UNSYMMETRICAL STILBENES AND 3-ARYLISOQUINOLONES

DOI: 10.1016/S0040-4039(00)87233-0

Source and publish data:

Tetrahedron Letters p. 1957 - 1960 (1982)

Update date:2022-08-04

Topics: Synthesis

Authors:

Girling, I. R.

Widdowson, D. A.

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Article abstract of DOI:10.1016/S0040-4039(00)87233-0

A series of cyclopalladated t-butylimines of aromatic aldehydes were reacted with styrene to give o-formylstilbenes in high yield.The N-methylimines of these were converted to 3-aryl-N-methyl-isoquinolones by oxidation with mercuric acetate.

Full text of DOI:10.1016/S0040-4039(00)87233-0

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