3,3-DIALKYL-2-PHOSPHINOYLOXAZIRIDINES: SYNTHESIS AND DETERMINATION OF THE BARRIER TO NITROGEN INVERSION

DOI: 10.1016/S0040-4039(00)95169-4

Source and publish data:

Tetrahedron Letters p. 235 - 238 (1989)

Update date:2022-07-29

Topics:

Authors:

Jennings, W. Brian

Watson, Stephen P.

Boyd, Derek R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95169-4

3,3-Dialkyl-2-diphenylphosphinoyloxaziridines, prepred by the oxidation of N-diphenylphosphinoyl imines with the 3-chloroperoxybenzoic acid-KF complex, have very low barriers to inversion at nitrogen (ΔG(act) 12.6-13.3 kcal mol^-1).

Full text of DOI:10.1016/S0040-4039(00)95169-4

Products guided by the article

Product name:C₁₅H₁₆NOP

Cas No:82944-80-7

R&D Labs maybe for 82944-80-7

guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province

Relevant to this article

Structure, dynamics and catalytic activity of palladium(II) complexes with imidazole ligands

Doi:10.1016/j.ica.2010.08.037
(2010)
Tandem bis-aldol reaction of ketones: A facile one-pot synthesis of 1,3-dioxanes in aqueous medium

Doi:10.1021/jo701337j
(2007)
SYNTHESIS OF FLUORINATED DERIVATIVES OF DIBENZOPYRENE

Doi:10.1016/S0022-1139(00)82272-1
(1982)
cis-Dichlorobisplatinum(II)

Doi:10.1107/S0567740882009054
(1982)
Selective Dealkylation of Bisbenzenes: Elimination-Substitution Competition with Methoxide and Methanethiolate Ions in Hexamethylphosphoric Triamide

Doi:10.1055/s-1982-29844
(1982)
Vanadium(IV) Porphyrins: Syntyhesis and Spectrochemical Characterization of Dihalogenovanadium(IV) Porphyrins. Extended X-Ray Absorption Fine Structural Study of Dibromo(2,3,7,8,12,13,17,18-octaethylporphyrinato)vanadium(IV)

Doi:10.1039/DT9820001451
(1982)

Article Doi