3,3-DIALKYL-2-PHOSPHINOYLOXAZIRIDINES: SYNTHESIS AND DETERMINATION OF THE BARRIER TO NITROGEN INVERSION

DOI: 10.1016/S0040-4039(00)95169-4

Source and publish data:

Tetrahedron Letters p. 235 - 238 (1989)

Update date:2022-07-29

Topics:

Authors:

Jennings, W. Brian

Watson, Stephen P.

Boyd, Derek R.

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Article abstract of DOI:10.1016/S0040-4039(00)95169-4

3,3-Dialkyl-2-diphenylphosphinoyloxaziridines, prepred by the oxidation of N-diphenylphosphinoyl imines with the 3-chloroperoxybenzoic acid-KF complex, have very low barriers to inversion at nitrogen (ΔG(act) 12.6-13.3 kcal mol^-1).

Full text of DOI:10.1016/S0040-4039(00)95169-4

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