Tetrahedron Letters p. 235 - 238 (1989)
Update date:2022-07-29
Topics:
Jennings, W. Brian
Watson, Stephen P.
Boyd, Derek R.
3,3-Dialkyl-2-diphenylphosphinoyloxaziridines, prepred by the oxidation of N-diphenylphosphinoyl imines with the 3-chloroperoxybenzoic acid-KF complex, have very low barriers to inversion at nitrogen (ΔG(act) 12.6-13.3 kcal mol-1).
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