3,3-DIALKYL-2-PHOSPHINOYLOXAZIRIDINES: SYNTHESIS AND DETERMINATION OF THE BARRIER TO NITROGEN INVERSION

DOI: 10.1016/S0040-4039(00)95169-4

Source and publish data:

Tetrahedron Letters p. 235 - 238 (1989)

Update date:2022-07-29

Topics:

Authors:

Jennings, W. Brian

Watson, Stephen P.

Boyd, Derek R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95169-4

3,3-Dialkyl-2-diphenylphosphinoyloxaziridines, prepred by the oxidation of N-diphenylphosphinoyl imines with the 3-chloroperoxybenzoic acid-KF complex, have very low barriers to inversion at nitrogen (ΔG(act) 12.6-13.3 kcal mol^-1).

Full text of DOI:10.1016/S0040-4039(00)95169-4

Products guided by the article

Product name:C₁₅H₁₆NOP

Cas No:82944-80-7

R&D Labs maybe for 82944-80-7

Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Structure, dynamics and catalytic activity of palladium(II) complexes with imidazole ligands

Doi:10.1016/j.ica.2010.08.037
(2010)
Tandem bis-aldol reaction of ketones: A facile one-pot synthesis of 1,3-dioxanes in aqueous medium

Doi:10.1021/jo701337j
(2007)
SYNTHESIS OF FLUORINATED DERIVATIVES OF DIBENZOPYRENE

Doi:10.1016/S0022-1139(00)82272-1
(1982)
cis-Dichlorobisplatinum(II)

Doi:10.1107/S0567740882009054
(1982)
Selective Dealkylation of Bisbenzenes: Elimination-Substitution Competition with Methoxide and Methanethiolate Ions in Hexamethylphosphoric Triamide

Doi:10.1055/s-1982-29844
(1982)
Vanadium(IV) Porphyrins: Syntyhesis and Spectrochemical Characterization of Dihalogenovanadium(IV) Porphyrins. Extended X-Ray Absorption Fine Structural Study of Dibromo(2,3,7,8,12,13,17,18-octaethylporphyrinato)vanadium(IV)

Doi:10.1039/DT9820001451
(1982)

Article Doi