REARRANGEMENTS OF N-ACYL-2-AZA-1,5-HEXADIENES: APPLICATION TO SYNTHESES OF TRAECHELANTHAMIDINE AND SUPINIDINE

DOI: 10.1016/S0040-4039(00)87451-1

Source and publish data:

Tetrahedron Letters p. 2761 - 2764 (1982)

Update date:2022-08-04

Topics: Syntheses Rearrangements

Authors:

Hart, David J.

Yang, Teng-Kuei

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Article abstract of DOI:10.1016/S0040-4039(00)87451-1

Efficient syntheses of the pyrrolizidine bases traechelanthamidine (4) and supinidine (5) via an N-acyliminium ion rearrangement-cyclization are described.

Full text of DOI:10.1016/S0040-4039(00)87451-1

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