Tetrahedron Letters p. 2585 - 2588 (1991)
Update date:2022-08-02
Topics:
Barton
Jaszberenyi
Theodorakis
Reaction of methanesulfonyl cyanide or p-toluenesulfonyl cyanide with alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) gives sulfinates in good yield. A mechanistic scheme involving sulfinyl cyanates is suggested.
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