Synthesis of 2-aryl derivatives of pentaborane(9)

DOI: 10.1021/ic00142a002

Source and publish data:

Inorganic Chemistry p. 4117 - 4121 (1982)

Update date:2022-08-04

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Authors:

Heppert, Joseph A.

Gaines, Donald F.

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Article abstract of DOI:10.1021/ic00142a002

A series of 2-aryl derivatives of B₅H₉ have been prepared via aluminum chloride catalyzed electrophilic substitution by 2-ClB₅H₈ on various alkylbenzenes. Analyses of ¹H NMR spectra suggest that the site of attack of the B₅H₈ moiety is controlled by steric interactions.

Full text of DOI:10.1021/ic00142a002

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