Tetrahedron Letters p. 3143 - 3146 (1982)
Update date:2022-08-04
Topics:
Stevenson, J. W. Sam
Bryson, T. A.
(1) 1,5-Dienes are readily prepared by titanium mediated methylenation of allyl esters, Claisen rearrangement followed by a second methylene transfer reaction. (2) The same 1,5-diene may be approached in "one pot" combining an allyl acetate and 3 equivalents biscyclopentadienyl-titanium-μ-chloro-μ-methylidene-bismethyl aluminium.
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Doi:10.1016/S0040-4039(00)87333-5
(1982)Doi:10.1016/S0040-4039(00)78698-9
(1980)Doi:10.1021/acs.orglett.8b01495
(2018)Doi:10.1021/jo00149a003
(1983)Doi:10.1002/jhet.5570190428
(1982)Doi:10.1139/v82-299
(1982)
