REGIOCHEMISTRY AND STEREOCHEMISTRY OF OXIRANE RING-OPENING WITH SILYL HALIDES

DOI: 10.1016/S0040-4039(00)87391-8

Source and publish data:

Tetrahedron Letters p. 2543 - 2546 (1982)

Update date:2022-08-02

Topics:

Authors:

Detty, Michael R.

Seidler, Mark D.

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Article abstract of DOI:10.1016/S0040-4039(00)87391-8

The ring-opening of various styrene and stilbene oxides with silyl halides was examined.The regiochemistry of ring-opening was independent of the silyl halide used, but the stereochemistry of ring-opening was sensitive to both the choice of halide and the steric bulk of groups attached to silicon.

Full text of DOI:10.1016/S0040-4039(00)87391-8

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