Helvetica Chimica Acta p. 191 - 200 (1984)
Update date:2022-07-30
Topics:
Thomas, Alan F.
Lander-Schouwey, Marina
(3-Cyclohexenyl)diallylcarbinols undergo a thermal retro-ene reaction to give crotonylcyclohexenes at ca. 200 degC.A side-reaction is an ene reaction to give bicyclo<3.3.1>nonanes.These become the main products above 300 degC.The stereochemistry of 2-allyl-1,4,6-trimethylbicyclo<3.3.1>-6-nonen-2-ols and related compounds is discussed, and a case is described in which the allyl group is not freely rotating.
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