Synthesis p. 2799 - 2804 (2004)
Update date:2022-08-05
Topics:
Kohyama, Naoki
Katashima, Tomoyuki
Yamamoto, Yukio
Novel 2-aryl AICAR (5-Amino-1-β-D-ribofuranosylimidazole-4- carboxamide) derivatives 8 were synthesized via the Suzuki-Miyaura cross-coupling reactions of 8-bromoadenosine. Following conversion of the adenine moiety of 4 to hypoxanthine (5) and the introduction of a MEM group, hydrolysis of 7 gave desired 2-aryl AICAR derivatives 8.
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