Regiochemical Aspects in the Reaction of 2,3,5-Tri-O-benzoyl-D-ribofuranosyl Acetate with Silyl Enol Ethers Catalyzed by Stannic Chloride

DOI: 10.1016/S0040-4039(00)87428-6

Source and publish data:

Tetrahedron Letters p. 2673 - 2676 (1982)

Update date:2022-08-05

Topics:

Authors:

Yokoyama, Yayoi S.

Elmoghayar, M. R. H.

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(00)87428-6

In the reaction with silyl enol ethers catalyzed by stannic chloride, 2,3,5-tri-O-benzoyl-D-ribofuranosyl acetate behaves as an ambident electrophile; silyl enol ethers of ketones having α-hetero substituents afford C-1 adducts, whereas those of usual acy

Full text of DOI:10.1016/S0040-4039(00)87428-6

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