Use of Allyltrimethylsilane in the Formation of Potential C-Nucleoside Precursors

DOI: 10.1021/jo00147a015

Source and publish data:

Journal of Organic Chemistry p. 5115 - 5120 (1982)

Update date:2022-08-04

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Authors:

Cupps, Thomas L.

Wise, Dean S.

Townsend, Leroy B.

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Article abstract of DOI:10.1021/jo00147a015

The soft nucleophile allyltrimethylsilane raeacted with 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose under Lewis acid catalysis to afford the novel allyl sugar 4,7-anhydro-1,2,3-trideoxy-5,6,8-tri-O-benzoyl-D-altro(allo)-oct-1-ene (1) as an anomeric mi

Full text of DOI:10.1021/jo00147a015

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