A METHOD FOR METHYLIDENATION AND ETHYLIDENATION OF AN ALLYLIC THIOETHER LEADING TO A 2,3-SIGMATROPIC REARRANGEMENT. FAILURE OF THE SIMMONS-SMITH REACTION IN THE PRESENCE OF THIOETHERS

DOI: 10.1016/S0040-4039(00)87522-X

Source and publish data:

Tetrahedron Letters p. 3019 - 3022 (1982)

Update date:2022-09-26

Topics:

Authors:

Kosarych, Zenyk

Cohen, Theodore

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87522-X

Allylic phenylthioethers are converted in one step to homoallylic phenylthioethers by treatment with methylene iodide or ethylidene iodide in the presence of diethylzinc but not zinc-copper or zinc-silver couples; furthermore, Simmons-Smith cyclopropanati

Full text of DOI:10.1016/S0040-4039(00)87522-X

Products guided by the article

Product name:((1R,5S)-5-Isopropenyl-2-methyl-cyclohex-2-enylmethylsulfanyl)-benzene

Cas No:83577-66-6

R&D Labs maybe for 83577-66-6

NanJing Rate Biochemicals CO., LTD

Contact:+86-25-84931986

Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Changzhou Welton Chemical Co., Ltd,

Contact:0086-519-85910828,85920537,85912897

Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】

website:http://www.chemboss.com.cn

Contact:+86-531-58591595

Address:No2.Hualong Road, Jinan, China
Jinan Finer Chemical Co., Ltd

website:https://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industrial Park, Jinan City, China
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China

Relevant to this article

Rate of cyclization of perfluoro-4-oxa-5-hexenyl radical. Use of tributylgermanium hydride as an effective H-transfer agent for perfluoro-n-alkenyl radicals

Doi:10.1021/jo960395y
(1996)
Mechanism of Proton Removal from Intramolecularly Hydrogen-Bonded (Phenylazo)resorcinol Monoanions

Doi:10.1021/ja00342a074
(1983)
Wittig Olefination via Reaction of Fluorine-Containing Phosphoranium Salts and F-Acyl Fluorides. A New Approach to Fluoroolefin Synthesis

Doi:10.1021/ja00341a070
(1983)
Anthracyclines and related substances. IV. A novel regio- and stereoselective total synthesis of 7-epidaunomycinone and daunomycinone

Doi:10.1016/S0040-4039(00)87730-8
(1982)
Access to Unprotected β-Fluoroalkyl β-Amino Acids and Their α-Hydroxy Derivatives

Doi:10.1021/acs.orglett.9b00622
(2019)
One step synthesis of 2-alkenylchromanes via inverse electron-demand Hetero-Diels–Alder reaction of o-quinone methide with unactivated dienes

Doi:10.1016/j.tet.2016.10.027
(2016)

Article Doi