A METHOD FOR METHYLIDENATION AND ETHYLIDENATION OF AN ALLYLIC THIOETHER LEADING TO A 2,3-SIGMATROPIC REARRANGEMENT. FAILURE OF THE SIMMONS-SMITH REACTION IN THE PRESENCE OF THIOETHERS

DOI: 10.1016/S0040-4039(00)87522-X

Source and publish data:

Tetrahedron Letters p. 3019 - 3022 (1982)

Update date:2022-09-26

Topics:

Authors:

Kosarych, Zenyk

Cohen, Theodore

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87522-X

Allylic phenylthioethers are converted in one step to homoallylic phenylthioethers by treatment with methylene iodide or ethylidene iodide in the presence of diethylzinc but not zinc-copper or zinc-silver couples; furthermore, Simmons-Smith cyclopropanati

Full text of DOI:10.1016/S0040-4039(00)87522-X

Products guided by the article

Product name:((1R,5S)-5-Isopropenyl-2-methyl-cyclohex-2-enylmethylsulfanyl)-benzene

Cas No:83577-66-6

R&D Labs maybe for 83577-66-6

QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Acorn PharmaTech Co., Ltd

Contact:86-25-58619180

Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Suzhou BEC Fine Chemicals Co., Ltd.

website:http://www.bek.com.cn

Contact:0512-68095917　 18913193865

Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside

Relevant to this article

Rate of cyclization of perfluoro-4-oxa-5-hexenyl radical. Use of tributylgermanium hydride as an effective H-transfer agent for perfluoro-n-alkenyl radicals

Doi:10.1021/jo960395y
(1996)
Mechanism of Proton Removal from Intramolecularly Hydrogen-Bonded (Phenylazo)resorcinol Monoanions

Doi:10.1021/ja00342a074
(1983)
Wittig Olefination via Reaction of Fluorine-Containing Phosphoranium Salts and F-Acyl Fluorides. A New Approach to Fluoroolefin Synthesis

Doi:10.1021/ja00341a070
(1983)
Anthracyclines and related substances. IV. A novel regio- and stereoselective total synthesis of 7-epidaunomycinone and daunomycinone

Doi:10.1016/S0040-4039(00)87730-8
(1982)
Access to Unprotected β-Fluoroalkyl β-Amino Acids and Their α-Hydroxy Derivatives

Doi:10.1021/acs.orglett.9b00622
(2019)
One step synthesis of 2-alkenylchromanes via inverse electron-demand Hetero-Diels–Alder reaction of o-quinone methide with unactivated dienes

Doi:10.1016/j.tet.2016.10.027
(2016)

Article Doi