A METHOD FOR METHYLIDENATION AND ETHYLIDENATION OF AN ALLYLIC THIOETHER LEADING TO A 2,3-SIGMATROPIC REARRANGEMENT. FAILURE OF THE SIMMONS-SMITH REACTION IN THE PRESENCE OF THIOETHERS

DOI: 10.1016/S0040-4039(00)87522-X

Source and publish data:

Tetrahedron Letters p. 3019 - 3022 (1982)

Update date:2022-09-26

Topics:

Authors:

Kosarych, Zenyk

Cohen, Theodore

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Article abstract of DOI:10.1016/S0040-4039(00)87522-X

Allylic phenylthioethers are converted in one step to homoallylic phenylthioethers by treatment with methylene iodide or ethylidene iodide in the presence of diethylzinc but not zinc-copper or zinc-silver couples; furthermore, Simmons-Smith cyclopropanati

Full text of DOI:10.1016/S0040-4039(00)87522-X

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