Journal of Organometallic Chemistry p. 123 - 136 (1982)
Update date:2022-08-04
Topics: Nucleophile
Riviere, P.
Castel, A.
Satge, J.
Substitution reactions of halogermanes under nucleophilic assistance of tertiary amines or diazo derivatives leading readily to various functional derivatives of germanium have been carried out.Dehydrohalogenation of acidic halohydrogemanes under nucleophilic assistance is a useful way to divalent species, and the germylenes formed are stabilized by complexation with the nucleophilic agent.The reactions proceed via intermediate halogermylanions which lead to the formation of more stable germylenes.The transient halogemylanions have been characterized by means of their nuclophilic additions to carbonyl derivatives.Nucleophilic substitutions of halogermanes using these germylanions lead to the formation of polygermanes.
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Shanghai united Scientific Co.,Ltd.
Contact:+86-21-53535353
Address:28F No.900 huaihai Road Shanghai China
website:http://www.shengmaochem.com
Contact:86-27-82853423, 82819281
Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Naturalin Bio-Resource Co., Ltd
website:http://www.naturalin.com
Contact:+86-0731-84430651
Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
Huaihua Baohua Biotechnology Co.,Ltd
website:http://www.baochengchem.com
Contact:86-519-82698291
Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
Doi:10.1016/j.bmc.2004.08.049
(2004)Doi:10.1016/j.bmcl.2005.10.019
(2006)Doi:10.1021/jo048762q
(2004)Doi:10.1002/ejoc.200500422
(2005)Doi:10.1021/jm020367+
(2003)Doi:10.1016/S0040-4039(01)81932-8
(1981)
