Correlated Rotation in 9-(2,4,6-Trimethylbenzyl)triptycenes. Direct and Roundabout Enantiomerization-Diastereomerization Processes

DOI: 10.1021/jo00156a017

Source and publish data:

Journal of Organic Chemistry p. 1233 - 1236 (1983)

Update date:2022-08-05

Topics:

Authors:

Yamamoto, Gaku

Oki, Michinori

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Article abstract of DOI:10.1021/jo00156a017

A dynamic NMR (DNMR) study on several singly peri-substituted 9-(2,4,6-trimethylbenzyl)triptycene derivatives revealed two rate processes: one exchanges the magnetic environments of the two o-methyl groups, and the other averages those of the benzylic met

Full text of DOI:10.1021/jo00156a017

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