SILICON IN ORGANIC SYNTHESIS. 16. A SHORT SYNTHESIS OF (+/-)-α-VETISPIRENE

DOI: 10.1016/S0040-4039(00)87576-0

Source and publish data:

Tetrahedron Letters p. 3227 - 3230 (1982)

Update date:2022-09-26

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Authors:

Yan, Tu-Hsin

Paquette, Leo A.

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Article abstract of DOI:10.1016/S0040-4039(00)87576-0

α-Vetispirene, a prototypical <4.5>spirobicyclic sesquiterpene, has been prepared in an efficient five-step reaction sequence beginning with α-trimethylsilyl cyclopropanecarboxaldehyde.A new desiliconative alkylation is featured.

Full text of DOI:10.1016/S0040-4039(00)87576-0

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