Journal of the Chemical Society, Dalton Transactions p. 1949 - 1952 (1982)
Update date:2022-07-30
Topics:
Rossi, Roberto
Duatti, Adriano
Magon, Luciano
Casellato, Umberto
Graziani, Rodolfo
Toniolo, Luigi
The compound a chelating ligand and that the two chlorine ligands are in cis position.Magnetic susceptibility measurements on the solids have demonstrated the presence of unpaired electrons, which affect the 1H n.m.r. spectra, the resonance signals being shifted up- and down-field with respect to SiMe4.The crystal structure of the title compound was determined by the X-ray analysis using counter data.The compound cristallizes in the monoclinic system, space group P21/a, with a=14.50(1), b=24.68(1), c=12.91(1) Angstroem, and β=108.5(4) deg for Z=4.The structure was refined to R=0.075.The rhenium atom is in a distorted octahedral co-ordination with two axial PPh3 groups, two cis-chlorine atoms, and the chelate ligand which forms a four-membered ring with the metal.
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd
Contact:+86-791-86899381
Address:Nanchang, Jiangxi, China
Contact:+86-025-52406782
Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
website:http://www.angchenchem.com
Contact:+86-510-88302099 82327577
Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
JiYi Chemical (Beijing) Co., Ltd.
Contact:+86-10-89385733
Address:Shilou Town of Fangshan District， Beijing
Contact:+86 21 5017 5386
Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Doi:10.1016/j.jfluchem.2014.07.025
(2014)Doi:10.1246/cl.1982.1595
(1982)Doi:10.1039/c39820000807
(1982)Doi:10.1016/S0008-6215(00)81803-0
(1982)Doi:10.1039/c39760000105
(1976)Doi:10.1016/S0040-4039(98)01788-2
(1998)
