Tetrahedron Letters p. 3291 - 3294 (1982)
Update date:2022-08-04
Topics:
Grootaert, Werner M.
De Clercq, Pierre J.
A short synthesis of a functionalized gibbane is described.The key-step involves the intramolecular Diels-Alder reaction of furan-diene 12, leading to a 1:3 ratio of two diastereoisomers, tentatively identified as 14a and 14b.The precursor 12 is obtained
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(2020)Doi:10.1039/b410931g
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(1982)Doi:10.1021/ja0679634
(2007)Doi:10.1021/acsmedchemlett.7b00387
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(1992)