Oxidation of Enol Silyl Ethers: Preparation of Aeginetolide, Dihydroactinidiolide, and Actinidiolide

DOI: 10.1021/jo00152a003

Source and publish data:

Journal of Organic Chemistry p. 422 - 425 (1983)

Update date:2022-07-31

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Authors:

Rubottom, George M.

Juve, Henrik D.

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Article abstract of DOI:10.1021/jo00152a003

The preparation of the C11-terpenic lactones aeginetolide (1), dihydroactinidiolide (2), and actinidiolide (3) by using 1,3,3-trimethyl-2-(trimethylsiloxy)cyclohexene (9) as a common precursor is discussed.The key steps in the synthetic route involve the sequential m-chloroperbenzoic acid (MCPBA) oxidation and acetylation of 9 and of the siloxy diene 13 derived from 9.

Full text of DOI:10.1021/jo00152a003

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