Journal of Organic Chemistry p. 422 - 425 (1983)
Update date:2022-07-31
Topics:
Rubottom, George M.
Juve, Henrik D.
The preparation of the C11-terpenic lactones aeginetolide (1), dihydroactinidiolide (2), and actinidiolide (3) by using 1,3,3-trimethyl-2-(trimethylsiloxy)cyclohexene (9) as a common precursor is discussed.The key steps in the synthetic route involve the sequential m-chloroperbenzoic acid (MCPBA) oxidation and acetylation of 9 and of the siloxy diene 13 derived from 9.
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Doi:10.1055/s-1982-30011
(1982)Doi:10.1016/S0022-328X(00)86917-X
(1982)Doi:10.1002/ardp.19863191007
(1986)Doi:10.1248/cpb.30.2840
(1982)Doi:10.1016/0008-6215(82)84027-5
(1982)Doi:10.1007/BF00506157
(1982)
