Relative Rate Constants for the Reactions of CF3OF with Olefins in Solution

DOI: 10.1021/jo00125a033

Source and publish data:

Journal of Organic Chemistry p. 6441 - 6443 (1995)

Update date:2022-09-26

Topics:

Authors:

Navarrini, W.

Russo, A.

Tortelli, V.

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Article abstract of DOI:10.1021/jo00125a033

The addition reactions of CF3OF to chloro fluoro olefins have been studied in solution at low temperature (-78, -105 deg C), and their relative rate constants have been determined using the kinetic approach of competition reactions.The reactivity and regio- and stereoselectivity are consistent with a free radical chain-propagating reaction in which the alkenes are attacked by the CF3O* radical generated by homolytic cleavage of the O-F bond in the CF3OF molecule.

Full text of DOI:10.1021/jo00125a033

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