Journal of Organic Chemistry p. 242 - 250 (1983)
Update date:2022-08-04
Topics:
Johri, Kamalesh K.
DesMarteau, Darryl D.
Reactions of CF3OX (X = Cl, F) with a variety of simple alkenes were carried out to compare the regio- and stereoselectivity of the additions to carbon-carbon double bonds.The observed addition products with CF3OCl are consistent with an electrophilic syn addition.With CF3OF the observed products indicate a different regioselectivity and low stereoselectivity, consistent with a free-radical addition.
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Doi:10.1107/S0567740882010103
(1982)Doi:10.1139/v82-437
(1982)Doi:10.1021/ja00343a011
(1983)Doi:10.1016/S0022-328X(00)84800-7
(1982)Doi:10.1021/om049297q
(2005)Doi:10.1039/b412030b
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