NMR AND THERMODYNAMIC INVESTIGATION OF THE REACTION OF SQUARE-PLANAR RHODIUM (I) COMPOUNDS WITH H2.

Article abstract of DOI:10.1021/ja00341a025

The reaction of square-planar rhodium(I) complexes of the general formula P(4-tolyl)//3)//2RhClB with H//2 has been investigated where B is P(4-tolyl)//3, pyridine, or tetrahydrothiophene. NMR studies confirm that in all cases the product geometry has the