Formation and Reactivity of Some Heterobinuclear Rhodium/Platinum Complexes with 2-(Diphenylphosphino)pyridine as a Bridging Ligand

Article abstract of DOI:10.1021/ja00342a024

Addition of Rh2(μ-Cl)2(CO)4 to cis-Pt(Ph2Ppy)2Cl2 forms , which on heating is converted into RhPt(Ph2Ppy)2(CO)Cl3.Treatment of RhPt(Ph2Ppy)2(CO)Cl3 with chlorine yields RhPt(Ph2Ppy)2(CO)Cl5.Spectroscopic data indicate that the o