
Journal of Organometallic Chemistry p. 171 - 176 (1982)
Update date:2022-08-04
Topics:
Eberl, Karl
Wolfgruber, Mathias
Sieber, Werner
Kreissl, Fritz Roland
Transition metal substituted ketenes react with water, methanol or dimethylamine to form acetic acids, methylacetate and dimethylacetamide with the metal in the α-position.This reaction proves to be of special importance for trapping thermolabile η1-ketene complexes, shown by means of a trifluorphosphane substituted representative.
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