Tetrahedron Letters p. 6681 - 6684 (1999)
Update date:2022-08-02
Topics:
Twyman, Lance J.
Sanders, Jeremy K. M.
The synthesis of two cyclic porphyrin dimers is reported. In each case the porphyrins are connected by a rigid butadiyne link, and a flexible alkyl chain tether. The length of this tether controls both the porphyrin-porphyrin distance, and porphyrin-porphyrin geometry. It is hoped that the extra flexibility designed within these molecules will enable them to act as general catalytic hosts for future study.
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