Tetrahedron Letters p. 925 - 928 (1981)
Update date:2022-07-31
Topics: Regioselectivity Yield NMR spectroscopy Mass spectrometry Nucleophile Electrophile Addition reaction DFT calculations Kinetics Solvent Effects Stereoselectivity Cycloaddition Reaction Activation Energy Pericyclic reaction Thermodynamics Transition state Conjugated system
Mayr, Herbert
Schuetz, Franz
Allenyl cations R-C=C=C(CH3)2(1+), generated in situ from propargyl chlorides and zinc chloride give monocyclic adducts or <3+4> and <2+4> cycloaddition products with various cycloalka-1,3-dienes.The mode of addition depends on R and the ring size of the
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Doi:10.1007/BF00506157
(1982)Doi:10.1016/S0008-6215(00)81888-1
(1982)Doi:10.1246/cl.1982.1579
(1982)Doi:10.1016/S0040-4039(01)91265-1
(1984)Doi:10.1021/jo00153a032
(1983)Doi:10.1055/s-1982-29963
(1982)
