ANNULATED SUGARS: FORMATION AND REACTIONS OF SOME CYCLOBUTANOHEXOPYRANOSIDES

DOI: 10.1016/S0008-6215(00)81888-1

Source and publish data:

Carbohydrate Research p. 41 - 50 (1982)

Update date:2022-07-31

Topics: Functionalization Reactions Synthetic methods Stereochemistry Catalysis Conformational Analysis Spectroscopic Characterization Kinetic Control Thermodynamic Control Ring Strain Formation

Authors:

Hicks, David Roy

Primeau, John Laurent

Fraser-Reid, Bert

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Article abstract of DOI:10.1016/S0008-6215(00)81888-1

The preparation of cyclobutanopyranosides by <2+2> photoadditions to methyl 2,3-dideoxy-2-C-methyl-α-D-glycero-hex-2-enopyranosid-4-ulose has been explored.Vinyl acetate adds readily, giving a mixture of diastereomers in good yield.Attempts to deacetylate

Full text of DOI:10.1016/S0008-6215(00)81888-1

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