BASISCHE METALLE. XL. RINGERWEITERUNG DURCH INTRAMOLEKULARE WANDERUNG EINES PHOSPHANLIGANDEN: SYNTHESE VON RHODIUM(III)-KOMPLEXEN MIT EINEM -METALLAHETEROCYCLUS

DOI: 10.1016/S0022-328X(00)86921-1

Source and publish data:

Journal of Organometallic Chemistry p. C65 - C70 (1982)

Update date:2022-08-05

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Authors:

Werner, H.

Hofmann, L.

Paul, W.

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Article abstract of DOI:10.1016/S0022-328X(00)86921-1

The reaction of C5H5Rh(PR3)P(OR')3 with CH2I2 affords the complexes I which readily undergo isomerization to yield I.The chelate complexes C5H5Rh(R2PCH2CH2PR2) (R = Me, Ph) also react with CH2I2 in the pre

Full text of DOI:10.1016/S0022-328X(00)86921-1

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Product name:[(C₅H₅)I(P(OCH₃)3)Rh(CH₂PCH₃(C₆H₅)2)]⁽¹⁺⁾*I^(1-)=[(C₅H₅)I(P(OCH₃)3)Rh(CH₂PCH₃(C₆H₅)2)]I

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