Journal of Organometallic Chemistry p. 75 - 78 (1981)
Update date:2022-07-30
Topics:
Nardelli, Mario
Pelizzi, Corrado
Predieri, Giovanni
Chiusoli, Gian Paolo
Bis(dinitrogen)bis<1,2-bis(diphenylphosphino)ethane>molybdenum reacts with chlorobenzene to form molybdenum chloro complexes and phenylated organic products.Benzene, biphenyl, o-, m-, p-chlorobiphenyl, a dihydro derivative of o-chlorobiphenyl, triphenylphosphine and diphenylvinylphosphine were formed.The isomer distribution of the chlorobiphenyls is close to that obtained by decomposition of 0.02 M benzoyl peroxide in chlorobenzene under dinitrogen.The cleavage of the Ph-Cl bond induced by the molybdenum-dinitrogen complex appears to give rise to the same homolytic reaction pattern.Phenylation of anisole and of triethyl phosphite has also been achieved with the same reagent.
View MoreGuangzhou Flower's Song Fine Chemical CO,. Ltd
Contact:+86-20-87475199
Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Yibin Hope Pharmaceutical Co., Ltd.
Contact:+86-831-5109851 86-831-5109836
Address:Luolong Industrial Zone,Nanxi, Yibin City, Sichuan, China. | Email: wishmarketing@gmail.com | Website: http://www.hopepharma.cc/
Hunan Shineway Enterprise Co., Ltd.
Contact:+86-731-86303875
Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Shanghai Norky Pharmaceutical Co., LTD.
website:http://www.norkypharm.com
Contact:86-21-61075300
Address:1165 Jiangning Road, Office 1502, Shanghai, China
Zhejiang Linhai Xinhua Chemicals Factory
Contact:0086-13661858911
Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Doi:10.1016/S0040-4039(00)87647-9
(1982)Doi:10.1016/j.ejmech.2004.10.007
(2005)Doi:10.1039/c8ob02229a
(2018)Doi:10.1021/ol0476220
(2005)Doi:10.1021/jo01311a001
(1980)Doi:10.1021/ja035182m
(2005)