REACTION DE L'ACIDE PERCHLORIQUE SUR LES PHENYLACETYLENES SUBSTITUES. MISE EN EVIDENCE D'UN MECANISME IONIQUE ET RADICALAIRE

DOI: 10.1016/S0040-4039(00)87647-9

Source and publish data:

Tetrahedron Letters p. 3483 - 3486 (1982)

Update date:2022-07-30

Topics:

Authors:

Montheard, Jean-Pierre

Camps, Marcel

Benzaid, Ahmed

Pascal, Jean-Louis

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Article abstract of DOI:10.1016/S0040-4039(00)87647-9

We have studied the reaction of perchloric acid in acetic acid medium on some substituted phenylacetylenes.The ionic and radicalar mechanism is in agreement with the formation of and alkenyl perchlorate which is decomposed according to an homolytic process.

Full text of DOI:10.1016/S0040-4039(00)87647-9

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