STANNOUS TRIFLATE: A FACILE CROSS-ALDOL REACTION BETWEEN TWO KETONES VIA DIVALENT TIN ENOLATES

DOI: 10.1246/cl.1982.1459

Source and publish data:

Chemistry Letters p. 1459 - 1462 (1982)

Update date:2022-08-05

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Authors:

Stevens, Rodney W.

Iwasawa, Nobuharu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1982.1459

Divalent tin enolates, formed from stannous triflate and ketones, react with a second ketone under mild conditions to afford the corresponding cross-aldol products in good to excellent yields.In the case of the cross-coupling with aromatic ketone, enhance

Full text of DOI:10.1246/cl.1982.1459

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