Substitution and Isomerisation Reactions at Platinum(II) involving Halide, Tertiary Phosphine, Carbonyl, and Isonitrile Ligands

DOI: 10.1039/DT9820002261

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2261 - 2264 (1982)

Update date:2022-08-05

Topics: Carbonyl Ligands Tertiary Phosphine Ligands Isonitrile Ligands

Authors:

Cross, Ronald J.

Phillips, Ian G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9820002261

Carbon monoxide catalyses trans to cis isomerisations of (L = tertiary phosphine) in chloroform solution.The process involves formation of five-co-ordinate intermediates from which halide or tertiary phosphine can be eliminated, giving trans-(1+) or cis- respectively.Structure changes appear to be by pseudo-rotations rather than by consecutive displacements.A number of isonitrile complexes undergo similar reactions.Halide-bridged cations (2+) formed by halide extraction from cis- by Ag(1+) enter rapid (n.m.r. time-scale) exchange processes with the latter complexes at ambient temperatures.Halide elimination from cis- by solvent chloroform appears to initiate the process.The trans isomers do not participate in the exchange.

Full text of DOI:10.1039/DT9820002261

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans-chlorobis(tributylphosphine)(phenylisocyanide)platinum trifluoromethanesulphonate

Cas No:84534-84-9

R&D Labs maybe for 84534-84-9

Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.

Relevant to this article

Preparation and properties of AzaTCNQ^- anion salts and mixed AzaTCNQ^-/ TCNQ^{{minus sign, dot below}}/TCNQ salts of some tetrakis(isocyanide)rhodium(I) cation, and x-ray crystal structure of the AzaTCNQ^--tetrakis(2,6-dimethylphenylisocyanide)rhodium(I)⁺ salt

Doi:10.1016/S0020-1693(00)81916-7
(1982)
PREMIER HETEROALLENE STABLE COMPORTANT UN ATOME DE PHOSPHORE DICOORDONNE.

Doi:10.1016/S0040-4039(00)85751-2
(1982)
A facile synthesis of novel polycyclic spiropyrrolidine oxindoles incorporating the 1,3-dipolar cycloaddition of azomethine ylides

Doi:10.1080/00397911.2020.1799011
(2020)
Synthesis and biological activity of some new aminoacylcarbazole derivatives. Part I

Doi:10.1002/jhet.5570190509
(1982)
The comparison in enantioseparation ability of the chiral stationary phases with single and mixed selector-The selectors derived from two D -tartrates

Doi:10.1002/chir.20904
(2011)
Opioid peptidomimetics: Leads for the design of bioavailable mixed efficacy μ opioid receptor (MOR) agonist/δ opioid receptor (DOR) antagonist ligands

Doi:10.1021/jm400050y
(2013)

Article Doi